Single-crystal X-ray study T = 294 K Mean '(C±C) = 0.007 A Ê R factor = 0.049 wR factor = 0.069 Data-to-parameter ratio = 20.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
(4,6-Dimethylpyrimidine-2-thiolato)(triphenylphosphine)gold(I)
✍ Scribed by Schulz Lang, Ernesto ;Fernandes Jr, Ramão Marceli ;Lemos, Sebastião Souza ;Schulz Lang, Leonardo ;Burrow, Robert Alan
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 168 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, [Ru(C 4 H 3 N 2 S) 2 (C 18 H 15 P) 2 ]ÁCHCl 3 , the Ru atom has a distorted octahedral environment formed by two S and two N atoms from the pyrimidine-2-thiolate ligands and two P atoms from the triphenylphosphine ligands. Intramolecularinteractions between the pyrimidine and
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.011 A Ê R factor = 0.061 wR factor = 0.139 Data-to-parameter ratio = 19.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The reaction of cinnamoyl isothiocyanate and aniline gave a the title cyclized thiourea, C 13 H 16 N 2 S. There are two molecules in the asymmetric unit. The pyrimidine-2-thione moiety in each molecule is almost perpendicular to the phenyl group. The molecules are linked by two intermolecular NÐHÁ Á