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{4-Chloro-2′-[(3-methoxy-2-oxido­phenyl)­methyl­idene]­benzohydr­azido}(pyridine)copper(II)

✍ Scribed by Ali, Hapipah ;Khamis, Nur Ashikin ;Basirun, W. Jefri ;Yamin, Bohari M.

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
191 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis

The molecular structure of the title compound, (I), shown with 50% probability displacement ellipsoids.

📜 SIMILAR VOLUMES

{4-Chloro-2′-[1-(5-chloro-2-oxido­phenyl
{4-Chloro-2′-[1-(5-chloro-2-oxido­phenyl)­ethyl­idene-κ3O,N2′,O′]­benzhydr­azido}tris­(pyridine-κN)­nickel(II) pyridine solvate
✍ Ali, Hapipah ;Khamis, Nur Ashikin ;Basirun, W. Jefri ;Yamin, Bohari M. 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 164 KB

The crystal structure of the title compound, [Ni(C 15 H 10 Cl 2- N 2 O 2 )(C 5 H 5 N) 3 ]ÁC 5 H 5 N, is built of molecules of a mononuclear nickel complex and uncoordinated solvent pyridine molecules. The Ni II atom in the complex is coordinated by two O and one N atoms of the meridional tridentate

Bis{2′-[1-(2-hydroxy-5-chloro­phenyl)­et
Bis{2′-[1-(2-hydroxy-5-chloro­phenyl)­ethyl­idene]­benzohydr­azido-κ2O,N2′}bis­(pyridine-κN)­zinc(II)
✍ Ali, Hapipah ;Khamis, Nur Ashikin ;Yamin, Bohari. M. 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 429 KB

The title compound, [Zn(C 15 H 13 ClN 2 O 2 ) 2 (C 5 H 5 N) 2 ], is a centrosymmetric monomer with octahedral geometry about the Zn atom. The molecule is stabilized by intermolecular CÐ HÁ Á ÁO and CÐHÁ Á ÁCl interactions, so forming a threedimensional network.

[1-(5-Chloro-2-oxido­phenyl)­ethanone 4-
[1-(5-Chloro-2-oxido­phenyl)­ethanone 4-nitro­benzoyl­hydrazonato(2−)]tris­(pyridine)­nickel(II) pyridine solvate
✍ Ali, Hapipah ;Khamis, Nur Ashikin ;Basirun, W. Jefri ;Yamin, Bohari M. 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 331 KB

The double chelate ring in the title complex, [Ni(C 15 H 11 Cl-N 3 O 3 ) 2 ]ÁC 5 H 5 N, is essentially planar, with the O,N,O-donor atoms and a pyridine ligand N atom occuping the equatorial positions in a distorted octahedral environment about the Ni atom. The NÐNiÐN axial bond angle is 173.16 (8)