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(4-Acetyl­pyridine)(tetra­phenyl­porphyrinato)zinc(II)

✍ Scribed by Lipstman, Sophia ;George, Sumod ;Goldberg, Israel

Book ID
104486516
Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
217 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Zn(C 44 H 28 N 4 )(C 7 H 7 NO)], is a squarepyramidal five-coordinate zinc-porphyrin complex withacetylpyridine as the apical ligand. The intermolecular packing involves van der Waals forces, closestacking and C-HÁ Á Á contacts, revealing an interesting pairing of adjacent molecules related by inversion.

📜 SIMILAR VOLUMES

A di­methyl sulfoxide/chloro­form clathr
A di­methyl sulfoxide/chloro­form clathrate of (di­methyl sulfoxide)(tetra­phenyl­porphyrinato)­zinc(II)
✍ Vinodu, Mikki ;Goldberg, Israel 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 278 KB

Single-crystal X-ray study T = 110 K Mean '(C±C) = 0.003 A Ê Disorder in solvent or counterion R factor = 0.043 wR factor = 0.112 Data-to-parameter ratio = 14.8 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

A second polymorph of (5,10,15,20-tetra­
A second polymorph of (5,10,15,20-tetra­phenyl­porphyrinato)copper(II)
✍ He, Hong-Shan 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 191 KB

In the title compound, [Cu(C 44 H 28 N 4 )], the copper ion is located at the center of the centrosymmetric and perfectly planar porphyrin ring.