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Tetra­pyridine­di­thio­cyanato­zinc(II)

✍ Scribed by Wu, Chuan-Bao

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
304 KB
Volume
60
Category
Article
ISSN
1600-5368

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Tetra­pyridine­di­thio­cyanato­copper(II
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The title compound, [Cu(NCS) 2 (C 5 H 5 N) 4 ], is a mononuclear copper(II) complex. The Cu II atom, lying on an inversion center, is six-coordinated by four pyridine N atoms and by another two N atoms of two thiocyanate anions in a slightly distorted octahedral geometry.

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The crystal structure of the title copper(II) complex, [Cu(NCS) 2 (C 5 H 5 N) 4 ], shows a tetragonally distorted octahedral coordination about the central copper(II) ion. The Cu ion lies at a site with 1 symmetry.

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In the title complex, [Cd(NCS) 2 (C 5 H 5 N) 4 ], the Cd II atom lies on a center of inversion. It is coordinated by four N atoms from four pyridines and two N atoms from two isothiocyanate ions and has a slightly distorted octahedral geometry.