## Abstract (25S)–5α‐cholestane‐3β, 26‐diol [2,4,2′,4′–^3^H~4~] was synthesized by hydrogenation of neotigogenin acetate 2, followed by acetylation to (25S)‐5α‐furostane‐3β, 26‐diol diacetate 5; this was oxidized to (25S)–16–22‐dioxo‐5α‐cholestane‐3β, 26‐diol diacetate 6. Clemmensen reduction of th
✦ LIBER ✦
3β-Methoxy-5α-cholestane-4β,5α-diol and related compounds
✍ Scribed by T.H. Campion; G.A. Morrison
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- French
- Weight
- 177 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0040-4039
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## ABSTRAm A facile and regiocontrolled procedure for the preparation of S~-cholestane-3a,7c,l2~,25-tetrol-3-O-fi-o-glucuronide and its corresponding C-26 analogue is described. The method involves direct coupling of bile alcohols, namely, 5/3-cholestane-3rY,7~,12a,25-tetrol and 24-nor-Sp-cholesta