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Actions of epoxides - XXII. 4α-hydroxy compounds from 4β, 5-epoxy-5β-cholestane by BF 3-catalysed rearrangement

✍ Scribed by B.N. Blackett; J.M. Coxon; M.P. Hartshorn; K.E. Richards


Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
89 KB
Volume
10
Category
Article
ISSN
0040-4039

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The Westphalen rearrangement' of 38,68-substituted-cholestan-5u-ols (1) to give 5g-methyl-A'-compounds (2) has received considerable study2. No rearrangement products are obtained from 5J3-hydroxy-3, 6a-substituted-4, 6f3-methyl-5 or 6-keto-derivatives 6 . Recently Davies and Summers' reported t