[3,6,9,12,23-Pentaazatetracyclo[22.4.0.02,6.014,19]octacosa-1(28),12,14,16,18,24,26-heptaene-21,22-dione(2–)-κ5N6,N9,N12,N20,N23]copper(II)
✍ Scribed by Sun, Ya-Qiu ;Dong, Wen ;Yang, Guang-Ming ;Liao, Dai-Zheng
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 267 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 298 K Mean (C-C) = 0.005 A Disorder in solvent or counterion R factor = 0.045 wR factor = 0.101 Data-to-parameter ratio = 15.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title complex, [Cu(C 36 H 36 N 4 O 4 )(ClO 4 )](ClO 4 )ÁC 3 H 7 N, the coordination number of the Cu II atom is 5 and the coordination configuration is best described as distorted tetragonal-pyramidal. There is a 13-membered macrocyclic ring in the molecule. One perchlorate anion and the dime
The title compound, C 30 H 26 N 2 O 4 , crystallizes in space group P2 1 /n, with two crystallographically independent molecules in the asymmetric unit. Two of the phenyl rings are perpendicular to one another. The molecular structure is in¯uenced by strong NÐHÁ Á ÁO, NÐHÁ Á ÁN and CÐHÁ Á ÁO intramo