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Acetato[μ-10,21-dibutyl-3,6,14,17-tetraza­tri­cyclo­[17.3.1.18,12]tetra­cosa-1(23),2,6,8,10,12(24),13,17,19,21-deca­ene-23,24-diolato(2–)-κ4N3,N6,O23,O24:κ4N14,N17,O23,O24]dinickel(II) perchlorate acetonitrile hemisolvate

✍ Scribed by Zhou, Hong ;Pan, Zhi-Quan ;Zhang, Yan-Jiao


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
165 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis


Single-crystal X-ray study T = 298 K Mean (C-C) = 0.005 A Disorder in solvent or counterion R factor = 0.045 wR factor = 0.101 Data-to-parameter ratio = 15.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.


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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.006 A Ê Disorder in solvent or counterion R factor = 0.047 wR factor = 0.159 Data-to-parameter ratio = 15.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

(Perchlorato-κO)[3,6,14,21-tetra­aza-3,6
✍ Sun, Gang-Chun ;Li, Yi-Zhi ;Chen, Nai-Sheng ;Wang, Liu-Fang 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 273 KB

In the title complex, [Cu(C 36 H 36 N 4 O 4 )(ClO 4 )](ClO 4 )ÁC 3 H 7 N, the coordination number of the Cu II atom is 5 and the coordination configuration is best described as distorted tetragonal-pyramidal. There is a 13-membered macrocyclic ring in the molecule. One perchlorate anion and the dime