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[μ-2,10,15,23-Tetramethyl-3,6,9,12,13,16,19,22,25,26,27,28-dodecaazatricyclo[22.2.1.111,14]hexacosa-1(26),2,9,11(28),13,15,22,24(27)-octaene-12,25-diido-1κ5N13,N16,N19,N22,N25:2κ5N3,N6,N9,N12,N26]bis[diaquamanganese(II)] dichloride hexa­hydrate

✍ Scribed by Shen, Liang ;Zhang, Yi-Jian ;Sheng, Guo-Ding


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
413 KB
Volume
62
Category
Article
ISSN
1600-5368

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✍ Chu, Zhao-Lian ;Huang, Wei 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 387 KB

The title compound, [Zn 2 (C 22 H 20 Cl 2 N 4 O 2 )(H 2 O) 2 ](NO 3 ) 2 , was obtained by the ion-exchange reaction of a dinuclear zinc(II)-diperchlorate complex of the macrocycle with Zn(NO 3 ) 2 Á6H 2 O. The complex lies about a centre of symmetry and the coordination about the Zn atom is distorte