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(3,5-Dimethyl-1H-pyrazole-κN2)(4-oxidopent-3-en-2-one 2-hydroxy­benzoyl­hydrazonato-κ2N,O)copper(II)

✍ Scribed by Du, Kang-Kai ;Liu, Shi-Xiong

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
144 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The Cu II atom in the title complex, [Cu(C 12 H 12 N 2 O 3 )-(C 5 H 8 N 2 )], is coordinated by two carboxyl O atoms and one hydrazine N atom from the 4-oxidopent-3-en-2-one 2hydroxybenzoylhydrazone ligand (sph 2À ) and one N atom of 3,5-dimethylpyrazole, forming a distorted square-planar geometry.

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Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.003 A Ê Disorder in main residue R factor = 0.036 wR factor = 0.110 Data-to-parameter ratio = 12.6 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.