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{3,3′-[Ethane-1,2-diylbis(methylimino)]bis(propane-1-thiolato)}nickel(II)

✍ Scribed by Grapperhaus, Craig A. ;O'Toole, Martin G. ;Mashuta, Mark S.

Book ID
104491555
Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
495 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Ni(C 10 H 22 N 2 S 2 )], contains a squareplanar Ni center coordinated by the tetradentate ligand 3,3 0 -[ethane-1,2-diylbis(methylimino)]dipropane-1-thiolate. Upon chelation, the N 2 S 2 ligand generates one five-membered chelate ring containing the N donors and two six-membered chelate rings in chair conformations, each containing one N and one S donor. The cis S donors, which are not directly linked together, form an acute S-Ni-S angle of 82.965 (18) due to ligand constraints.

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