Crystal structure of [bis 1,2-(diphenylphosphino)ethane]-bis(pyridine-2-thiolato)ruthenium(II)
✍ Scribed by Edward R. T. Tiekink; Tarlok S. Lobana; Randhir Singh
- Publisher
- Springer
- Year
- 1991
- Tongue
- English
- Weight
- 289 KB
- Volume
- 21
- Category
- Article
- ISSN
- 1572-8854
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In the title compound, [PtI~2~(C~26~H~24~P~2~)]·2CH~2~Cl~2~, the PtI~2~(dppe) [dppe = 1,2-bis(diphenylphosphino)ethane] molecules possess twofold rotation symmetry. The Pt coordination displays a square-planar arrangement, with the sum of the angles around the Pt atom being 360.01 (2)°. The Pt—I dis
Acta Cryst. (2001). E57, m433±m434 slightly longer in the THF adduct than the corresponding distances in the CH 2 Cl 2 adduct [2.141 (1) and 2.156 (1) A Ê ], but both NiÐBr bonds are very similar. In this structure, there is a stacking interaction between the THF ring and the C121Ð C126 phenyl ring,