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31P CIDNP in the free radical reactions of dialkyl phosphites

✍ Scribed by Ya. A. Levin; A. V. Il'yasov; E. I. Goldfarb; E. I. Vorkunova

Book ID
102951760
Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
846 KB
Volume
5
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The polarisation of phosphorus nuclei (^31^P CIDNP) takes place during the homolytic reactions of dialkyl phosphites. The mechanisms of ^31^P CIDNP and the corresponding chemical reactions are discussed.

πŸ“œ SIMILAR VOLUMES

31P CIDNP in the reactions of phosphoran
31P CIDNP in the reactions of phosphoranyl radicals
✍ Ya. A. Levin; A. V. Il'yasov; E. I. Goldfarb; E. I. Vorkunova πŸ“‚ Article πŸ“… 1973 πŸ› John Wiley and Sons 🌐 English βš– 419 KB

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## Abstract Chemical polarisation of ^31^P nuclei was discovered and quantitatively measured in the peroxide‐phosphite system. The qualitative interpretation of the net polarisation of ^31^P nuclei and of its sign in the products of the radical reactions in the presence of phosphites is given withi