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The invention of radical reactions. Part 32. Radical deoxygenations, dehalogenations, and deaminations with dialkyl phosphites and hypophosphorous acid as hydrogen sources

โœ Scribed by Barton, Derek H. R.; Jang, Doo Ok; Jaszberenyi, Joseph C.


Book ID
120319701
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
651 KB
Volume
58
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES


Radical deoxygenation and dehalogenation
โœ Satoshi Takamatsu; Satoshi Katayama; Naoko Hirose; Masaki Naito; Kunisuke Izawa ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 69 KB

Hypophosphorous acid and dialkyl phosphites are effective radical reducing agents for O-thiocarbonyl groups or halides at the sugar part of nucleoside derivatives and give the corresponding hydrocarbons in high yield.