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2D POLYMERIC COPPER(I) COMPLEXES. SYNTHESIS AND CHARACTERIZATIONS OF [Cu(pyza) 2X ] n ( X ═CN, NCS AND N 3 , AND pyza═PYRAZINECARBOXAMIDE) AND X-RAY CRYSTAL STRUCTURES OF THE CYANO AND THIOCYANATO COMPLEXES

✍ Scribed by Goher, Mohamed A. S.; Mautner, Franz A.


Book ID
126520822
Publisher
Taylor and Francis Group
Year
2001
Tongue
English
Weight
609 KB
Volume
53
Category
Article
ISSN
0095-8972

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Copper(I) complexes with a dibasic nitro
✍ Anne-Marie Larsonneur; Reine Turpin; Pierre Ferté; Paule Castan; Gerald Bernardi 📂 Article 📅 1994 🏛 Springer 🌐 English ⚖ 498 KB

The reaction of CuC1 or CuX 2 (X = C1 or NO3) with NPm (diphenylphosphinodiphenylaminomethane) yields molecular P-bonded copper(I) complexes of general formula CuL2X. These complexes are isostructural. For both complexes the coordination geometry around the copper atom is almost trigonal planar and