Synthesis, spectroscopy, and crystal structures of [Cu(ca 2 en) 2 ]ClO 4 (1) and [Cu(ca 2 en)(PPh 3 ) 2 ]ClO 4 (2) (ca 2 en N,N'-bis(trans-cinnamaldehyde)ethylenediimine) are reported. Compound 1 crystallizes in the orthorhombic space group Pbca, with a 12.5647( ), b 21.8203(11), c 27.992(2) Γ€, V 76
Synthesis and characterization of [Cu(Phca2en)(PPh3)X] (X=Cl, Br, I, NCS, N3) complexes: crystal structures of [Cu(Phca2en)(PPh3)Br] and [Cu(Phca2en)(PPh3)I]
β Scribed by Saeed Dehghanpour; Amir H. Mahmoudkhani; Mehdi Amirnasr
- Publisher
- Springer
- Year
- 2006
- Tongue
- English
- Weight
- 654 KB
- Volume
- 17
- Category
- Article
- ISSN
- 1040-0400
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## Abstract CuBr and Fe(OOCCH~3~)~2~ react with PhSeSiMe~3~ in acetonitrile in the presence of the diammonium salt [__n__Pr~3~N(CH~2~)~6~N__n__Pr~3~]Br~2~ to yield ionic [__n__Pr~3~N(CH~2~)~6~N__n__Pr~3~][CuFe~3~Br~3~(SePh)~6~]. The neutral complexes [Cu~5~Fe(SePh)~7~(PPh~3~)~4~] and [Cu~4~Fe~3~(Se