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Preparation and spectral characterization of copper(I) halide, nitrate and perchlorate complexes of pyrazinic acid and X-ray crystal structure of polymeric [Cu2(pyrazinic acid)2I2] · 3H2O

✍ Scribed by Mohamed A.S. Goher; Thomas C.W. Mak


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
733 KB
Volume
14
Category
Article
ISSN
0277-5387

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A series of rhenium(I) tricarbonyl complexes with the ligand 2,3,5,6-tetra(2-pyridyl)pyrazine (tppz) were synthesized and characterized crystallographically. Two different coordination modes were found when tppz functions as a monobidentate ligand. Rhenium(I) may be bound to tppz through pyrazine an