The molecule of the title compound, C 56 H 30 F 26 P 2 , is located on a twofold axis perpendicular to the central C-C bond of the binaphthyl group and the P atoms have the typical pseudotetrahedral geometry found for compounds of this type.
2,6-Bis({rac-1-[2-(diphenylphosphino)ferrocenyl]ethyl}aminocarbonyl)pyridine
✍ Scribed by Reddy, Pattubala A. N. ;Md, Nasiruzzaman Sk. ;Kim, Tae-Jeong
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 152 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the molecule of the title compound, C~25~H~27~N~3~, the two 2,6-dimethyl-substituted phenyl rings are connected to the pyridine ring __via__ the C=N imine bonds. Although the compound includes three N atoms, there are no obvious hydrogen-bond or π–π interactions in the crystal structure.
The title compound, C 23 H 26 ClN 5 O 2 , was synthesized by the reaction of 4- [(2,6-dimethylphenyl)aminocarbonylmethyl]piperazine and 5-chloromethyl-3-(2-chlorophenyl)-1,2,4oxadiazole. In the structure, there are intramolecular C-HÁ Á ÁN, N-HÁ Á ÁN and C-HÁ Á ÁO hydrogen bonds, and intermolecular
The title compound, [Au~2~Fe(C~38~H~37~NP~2~)(SCN)~2~], is a dinuclear gold(I) complex containing an unsymmetrical bidentate ferrocenyl–phosphine ligand. Selected geometrical parameters for the compound are Au—P = 2.265 (2) and 2.260 (3) Å, Au—S = 2.327 (3) and 2.313 (3) Å, and P—Au—S = 175.61 (9) a