2,3-Bis(2-tert-butylphenylimino)butane
✍ Scribed by Ferreira, Leonardo C. ;Filgueiras, Carlos Alberto L. ;Hörner, Manfredo ;Visentin, Lorenzo do C. ;Bordinhao, Jairo
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 212 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, C 24 H 32 N 2 , there is one half-molecule in the asymmetric unit, the other half being generated by inversion. All bond lengths and angles show normal values. The deviation from a planar arrangement can be attributed to non-classical hydrogen bonds and steric factors.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 180 K Mean '(C±C) = 0.012 A Ê Disorder in main residue R factor = 0.056 wR factor = 0.148 Data-to-parameter ratio = 6.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title molecule, C 20 H 24 N 2 , is centrosymmetric, crystallizing with the -N C(CH 3 )-C(CH 3 ) N-diimino group in a trans configuration. The crystal structure is stabilized by an intramolecular C-HÁ Á ÁN hydrogen-bonding interaction.