The title compound, C 18 H 14 F 6 N 2 , crystallizes with the -N C(CH 3 )-C(CH 3 ) N-diimino group around an inversion center in a trans configuration.
2,3-Bis(2-ethylphenylimino)butane
✍ Scribed by Martins, Roberto S. ;Filgueiras, Carlos A. L. ;Visentin, Lorenzo do C. ;Bordinhão, Jairo ;Ferreira, Leonardo C.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 342 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title molecule, C 20 H 24 N 2 , is centrosymmetric, crystallizing with the -N C(CH 3 )-C(CH 3 ) N-diimino group in a trans configuration. The crystal structure is stabilized by an intramolecular C-HÁ Á ÁN hydrogen-bonding interaction.
📜 SIMILAR VOLUMES
In the title compound, C 24 H 32 N 2 , there is one half-molecule in the asymmetric unit, the other half being generated by inversion. All bond lengths and angles show normal values. The deviation from a planar arrangement can be attributed to non-classical hydrogen bonds and steric factors.
1998 structure structure (organic substances) K 9000 25 -044 (2R,3R)-2,3-Dibenzyloxy-1,4-bis(diphenylphosphino)butane. -The absolute configuration of title compound (I) is determined by the Flack method. -(BEJA, A. M.;