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Bis(η3-2-tert-butyl-3-phenyl-1-trimethylsilyl-1-azaallyl)cobalt(II)

✍ Scribed by Yuan, Hai-Yan ;Tong, Hong-Bo ;Wei, Xue-Hong


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
140 KB
Volume
63
Category
Article
ISSN
1600-5368

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Bis[η3-2-tert-butyl-1,3-bis­(trimethyl­s
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The title compound, [Co(C 12 H 27 NSi 2 ) 2 ], is a homoleptic metal-3 -azaallyl complex, which has a center of symmetry. The Co-C bond distances are 2.100 (4) and 2.068 (4) A ˚, and the Co-N bond distance is 1.878 (3) A ˚.

Bis(1,2,3,4-η4-anthracene)cobaltate(1−)
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2-(4-tert-Butyl­benzyl)-3-phenyl­inden-1
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The title compound, C 26 H 24 O, was obtained from the reaction of 2-[(4-tert-butyl)phenylmethyl]-1,3-diphenylpropane-1,3dione with acetic anhydride. The reaction yielded 92% of the product. The crystal structure con®rms the formation of the ®ve-membered ring from the parent dione.