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1-tert.-Butyl-3-trimethylsilyl-4,4-dimethyl-2-phospha-1-tetrazen

✍ Scribed by Prof. Dr. Otto J. Scherer; Dipl.-Chem. Walter Gläßel


Publisher
John Wiley and Sons
Year
1975
Tongue
English
Weight
264 KB
Volume
87
Category
Article
ISSN
0044-8249

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Trisilane 7 has been synthesized as a potential photochemical precursor of tetra-tert-butylsilatetrahedrane (5) and/or tetra-tert-butylsilacyclobutadiene (6). Astonishingly, only one Si,Si bond is broken upon irradiation of 7 and the silacy-