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1,2,3,4-Tetra-tert-butyl-4-trimethylsilyl-4-sila-2-cyclobuten-1-yl: A Quantum Mechanical and ESR Study

✍ Scribed by Günther Maier; Armin Kratt; Andreas Schick; Hans Peter Reisenauer; Frédérique Barbosa; Georg Gescheidt

Publisher: John Wiley and Sons
Year: 2000
Tongue: English
Weight: 293 KB
Volume: 2000
Category: Article
ISSN: 1434-193X
DOI: 10.1002/1099-0690(200004)2000:7<1107::aid-ejoc1107>3.0.co;2-8

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✦ Synopsis

Trisilane 7 has been synthesized as a potential photochemical precursor of tetra-tert-butylsilatetrahedrane (5) and/or tetra-tert-butylsilacyclobutadiene (6). Astonishingly, only one Si,Si bond is broken upon irradiation of 7 and the silacy-

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