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ChemInform Abstract: Small Rings. Part 93. 1,2,3,4-Tetra-tert-butyl-4-trimethylsilyl-4-sila-2-cyclobuten-1-yl: A Quantum Mechanical and ESR Study.

✍ Scribed by Guenther Maier; Armin Kratt; Andreas Schick; Hans Peter Reisenauer; Frederique Barbosa; Georg Gescheidt

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
31
Category
Article
ISSN
0931-7597

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1,2,3,4-Tetra-tert-butyl-4-trimethylsily
1,2,3,4-Tetra-tert-butyl-4-trimethylsilyl-4-sila-2-cyclobuten-1-yl: A Quantum Mechanical and ESR Study
✍ Günther Maier; Armin Kratt; Andreas Schick; Hans Peter Reisenauer; Frédérique Ba 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 293 KB 👁 1 views

Trisilane 7 has been synthesized as a potential photochemical precursor of tetra-tert-butylsilatetrahedrane (5) and/or tetra-tert-butylsilacyclobutadiene (6). Astonishingly, only one Si,Si bond is broken upon irradiation of 7 and the silacy-