Bis[η3-2-tert-butyl-1,3-bis(trimethylsilyl)-1-azaallyl]cobalt(II)
✍ Scribed by Zhang, Yong ;Tong, Hong-Bo ;Liu, Dian-Sheng ;Zhou, Mei-Su ;Huang, Su-Ping
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 123 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, [Co(C 12 H 27 NSi 2 ) 2 ], is a homoleptic metal-3 -azaallyl complex, which has a center of symmetry. The Co-C bond distances are 2.100 (4) and 2.068 (4) A ˚, and the Co-N bond distance is 1.878 (3) A ˚.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 137 K Mean '(C±C) = 0.005 A Ê R factor = 0.048 wR factor = 0.134 Data-to-parameter ratio = 18.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê Disorder in main residue R factor = 0.064 wR factor = 0.195 Data-to-parameter ratio = 13.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.