(2,2'-Bipyridine)bis(thiocyanato-N)copper(II), [Cu(bipy)(NCS)2]
β Scribed by Parker, O. J. ;Wilson, B. L. ;Breneman, G. L.
- Book ID
- 114511378
- Publisher
- International Union of Crystallography
- Year
- 1994
- Tongue
- English
- Weight
- 296 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0108-2701
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π SIMILAR VOLUMES
Bis(2,2 0 0 0 -bipyridine N-oxide)bis(dicyanamido)copper(II)
In the title compound, [Cu(C 10 H 8 N 2 ) 2 (H 2 O)](BF 4 ) 2 , the Cu II atom is coordinated by four N atoms and one O atom in a distorted trigonal-bipyramidal geometry. The Cu-N bond lengths are in the range 1.982 (3)-2.124 (3) A Λ, while the Cu-O distance is 2.035 (4) A Λ. The structure is stabil
In the title complex, [CdBr 2 (C 10 H 8 N 2 ) 2 ], a crystallographic twofold rotation axis passes through the Cd II ion, which is sixcoordinated by four N atoms of two symmetry-related 2,2 0bipyridine ligands and two symmetry-related Br Γ anions.