Bis(2,2′-bipyridine N-oxide)bis(dicyanamido)copper(II)
✍ Scribed by Dai, Jian-Fang ;Liu, Fu-Ying ;Liu, Hui ;Sun, Bai-Wang ;Wang, Yi-Hong
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 401 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Bis(2,2 0 0 0 -bipyridine N-oxide)bis(dicyanamido)copper(II)
📜 SIMILAR VOLUMES
In the triclinic form of the title compound, [Cu(C 2 N 3 )(C 10 H 8 N 2 ) 2 ]ClO 4 , the Cu II center is coordinated by five N atoms in a distorted square-pyramidal geometry, which is different from that observed earlier in an orthorhombic polymorph of the same compound.
In the title compound, [Cu(C 10 H 8 N 2 ) 2 (H 2 O)](BF 4 ) 2 , the Cu II atom is coordinated by four N atoms and one O atom in a distorted trigonal-bipyramidal geometry. The Cu-N bond lengths are in the range 1.982 (3)-2.124 (3) A ˚, while the Cu-O distance is 2.035 (4) A ˚. The structure is stabil
l-N,N 0 0 0 -Bis(3-aminopropyl)oxamidato(2À)]bis[(2,2 0 0 0 -bipyridine)copper(II)] dinitrate