The title compound, [Ni(C~23~H~17~N~4~O)(N~3~)], was obtained by the reaction of the Schiff base ligand 2-[(tri-2-pyridylmethyl)iminomethyl]phenol with sodium azide and nickel(II) perchlorate in methanol solution. The Ni^II^ atom is four-coordinated by the phenolate O, the imine N and a pyridine N a
2-[(Tri-2-pyridylmethyl)iminomethyl]phenol
✍ Scribed by Li, Yin-Huai ;Gao, Jun
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 144 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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The title compound, C 12 H 17 N 3 O, was obtained by the direct solvent-free reaction of salicylaldehyde with 1-amino-4methylpiperazine. The piperazine ring adopts a chair conformation. In the crystal structure, strong intramolecular O-HÁ Á ÁN hydrogen bonds, weak intermolecular C-HÁ Á ÁO hydrogen b
The molecule of the title compound, C 14 H 12 BrNO 2 , crystallizes in a zwitterionic form, with a strong intramolecular N-HÁ Á ÁO hydrogen bond. The dihedral angle between the aromatic rings is 9.3 (3) . Intermolecular O-HÁ Á ÁO hydrogen bonds generate C(8) chains running parallel to the [100] dire
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