The title compound, C 18 H 12 F 3 N 3 OS 2 , was synthesized by the reaction of [(Z)-1-phenylmethylidene]{5-[3-(trifluoromethyl)phenyl]-1,3,4-thiadiazol-2-yl}amine and mercaptoacetic acid. In the structure there are intramolecular C-HÁ Á ÁS and C-HÁ Á ÁN and intermolecular C-HÁ Á ÁN hydrogen bonds.
(E)-2-[(1,2,3-Thiadiazol-5-yl)iminomethyl]phenol
✍ Scribed by Gao, Jin-Sheng ;Zhang, Shuang ;Hou, Guang-Feng ;Hou, Yan-Jun ;Yan, Peng-Fei
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 332 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, C 9 H 7 N 3 OS, the structure is stabilized by intramolecular O-HÁ Á ÁN and intermolecular C-HÁ Á ÁO and C-HÁ Á ÁN hydrogen bonds. The intermolecular hydrogen bonds link the molecules into a three-dimensional supramolecular network.
📜 SIMILAR VOLUMES
The title compound, C 13 H 18 N 2 O 2 , exists in the enol-imine tautomeric form with a strong intramolecular O-HÁ Á ÁN hydrogen bond [OÁ Á ÁN = 2.5795 (18) A ˚], and the morpholine ring adopts an almost perfect chair conformation.
The title compound, C 12 H 17 N 3 O, was obtained by the direct solvent-free reaction of salicylaldehyde with 1-amino-4methylpiperazine. The piperazine ring adopts a chair conformation. In the crystal structure, strong intramolecular O-HÁ Á ÁN hydrogen bonds, weak intermolecular C-HÁ Á ÁO hydrogen b