(E)-2-[(2-Morpholinoethylimino)methyl]phenol
✍ Scribed by Petek, Hande ;Albayrak, Çiğdem ;İskeleli, Nazan Ocak ;Ağar, Erbil ;Şenel, İsmet
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 118 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, C 13 H 18 N 2 O 2 , exists in the enol-imine tautomeric form with a strong intramolecular O-HÁ Á ÁN hydrogen bond [OÁ Á ÁN = 2.5795 (18) A ˚], and the morpholine ring adopts an almost perfect chair conformation.
📜 SIMILAR VOLUMES
The title compound, C 14 H 12 N 2 O 4 , exists as an enol-imine tautomer, in which a strong intramolecular O-HÁ Á ÁN hydrogen bond is formed. This study verifies the preference of the enol-imine tautomeric form in the solid state.
In the title compound, C 9 H 7 N 3 OS, the structure is stabilized by intramolecular O-HÁ Á ÁN and intermolecular C-HÁ Á ÁO and C-HÁ Á ÁN hydrogen bonds. The intermolecular hydrogen bonds link the molecules into a three-dimensional supramolecular network.
The title compound, C 12 H 17 N 3 O, was obtained by the direct solvent-free reaction of salicylaldehyde with 1-amino-4methylpiperazine. The piperazine ring adopts a chair conformation. In the crystal structure, strong intramolecular O-HÁ Á ÁN hydrogen bonds, weak intermolecular C-HÁ Á ÁO hydrogen b