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Azido{2-[(tri-2-pyridylmethyl)iminomethyl]phenolato}nickel(II)

✍ Scribed by Tian, Lai-Jin ;Yang, Hong-Jun ;Ni, Zhong-Hai

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 352 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807051793

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✦ Synopsis

The title compound, [Ni(C~23~H~17~N~4~O)(N~3~)], was obtained by the reaction of the Schiff base ligand 2-[(tri-2-pyridylmethyl)iminomethyl]phenol with sodium azide and nickel(II) perchlorate in methanol solution. The Ni^II^ atom is four-coordinated by the phenolate O, the imine N and a pyridine N atom of the Schiff base ligand, and by the terminal N atom of an azide ligand, forming a square-planar geometry. The other two pyridyl rings are oriented at an angle of 72.29 (11)° to each other.

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