2-[(Z)-(2,5-Dichlorophenyl)iminomethyl]-5-(diethylamino)phenol
✍ Scribed by Jasinski, Jerry P. ;Butcher, Ray J. ;Narayana, B. ;Swamy, M. T. ;Yathirajan, H. S.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 762 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title molecule, C 17 H 18 Cl 2 N 2 O, the angle between the mean planes of the 2,5-dichlorophenylimino and phenol groups is 19.5 (5) . The two ethyl groups adopt a synclinal conformation. The crystal structure is stabilized by intermolecularstacking interactions between adjacent 2,5dichlorophenyl rings, the distance between the centroids of interacting rings being 3.860 (8) A ˚. The molecules are stacked parallel to the a axis. In addition, an O-HÁ Á ÁN intramolecular hydrogen-bonding interaction between the phenol H atom and imino N atom is observed.
📜 SIMILAR VOLUMES
The molecule of the title compound, C 14 H 12 BrNO 2 , crystallizes in a zwitterionic form, with a strong intramolecular N-HÁ Á ÁO hydrogen bond. The dihedral angle between the aromatic rings is 9.3 (3) . Intermolecular O-HÁ Á ÁO hydrogen bonds generate C(8) chains running parallel to the [100] dire
The centrosymmetric title compound, C 24 H 34 N 4 O 4 , has been characterized structurally by 1 H NMR and X-ray crystallography. The two benzene rings are parallel to each other. The compound forms intramolecular hydrogen bonds, where the oxime group acts as a hydrogen-bond donor and the OH group a
In the title compound, C 9 H 7 N 3 OS, the structure is stabilized by intramolecular O-HÁ Á ÁN and intermolecular C-HÁ Á ÁO and C-HÁ Á ÁN hydrogen bonds. The intermolecular hydrogen bonds link the molecules into a three-dimensional supramolecular network.