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2-(Aminomethyl)pyridine−Phosphine Ruthenium(II) Complexes: Novel Highly Active Transfer Hydrogenation Catalysts

✍ Scribed by Baratta, Walter; Herdtweck, Eberhardt; Siega, Katia; Toniutti, Micaela; Rigo, Pierluigi

Book ID
120359633
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
192 KB
Volume
24
Category
Article
ISSN
0276-7333

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📜 SIMILAR VOLUMES

[2.2]PHANEPHOS-Ruthenium(II) complexes:
[2.2]PHANEPHOS-Ruthenium(II) complexes: Highly active asymmetric catalysts for the hydrogenation of β-ketoesters
✍ Philip J. Pye; Kai Rossen; Robert A. Reamer; R.P. Volante; Paul J. Reider 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 248 KB

The application of the planar chiral [2.2]PHANEPHOS ligand in the Ru(II)-catalyzed asymmetric hydrogenation of ~ketoesters gave up to 96% ee involving a practical and reproducible procedure using the defined and readily prepared [2.2]PHANEPHOS-Ru(lI)bis(trifluoroacetate) salt in the presence of a ha