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Cyclometalated Ruthenium(II) Complexes as Highly Active Transfer Hydrogenation Catalysts

✍ Scribed by Walter Baratta; Paolo Da Ros; Alessandro Del Zotto; Alessandra Sechi; Ennio Zangrando; Pierluigi Rigo

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
141 KB
Volume
43
Category
Article
ISSN
0044-8249

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## Abstract A library of organometallic compounds derived from primary and secondary amines cyclometalated by ruthenium(II), rhodium(III) and iridi‐ um(III) was tested in the asymmetric transfer hydrogenation of a number of ketones and imines. All compounds displayed high catalytic activity for the

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