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ChemInform Abstract: [2.2]PHANEPHOS-Ruthenium(II) Complexes: Highly Active Asymmetric Catalysts for the Hydrogenation of β-Ketoesters.

✍ Scribed by P. J. PYE; K. ROSSEN; R. A. REAMER; R. P. VOLANTE; P. J. REIDER

Publisher: John Wiley and Sons
Year: 2010
Weight: 34 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199837036

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✦ Synopsis

1998 stereochemistry stereochemistry (general, optical resolution) O 0030 37 -036 [2.2]PHANEPHOS-Ruthenium(II) Complexes: Highly Active Asymmetric Catalysts for the Hydrogenation of β-Ketoesters.

-Ru(II)-complexes of planar chiral [2.2]PHANEPHOS are found to be highly efficient catalysts for the asymmetric hydrogenation of β-ketoesters to the corresponding β-hydroxy esters. -(PYE, P.

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