𝔖 Bobbio Scriptorium
✦   LIBER   ✦

[2.2]PHANEPHOS-Ruthenium(II) complexes: Highly active asymmetric catalysts for the hydrogenation of β-ketoesters

✍ Scribed by Philip J. Pye; Kai Rossen; Robert A. Reamer; R.P. Volante; Paul J. Reider

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
248 KB
Volume
39
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

The application of the planar chiral [2.2]PHANEPHOS ligand in the Ru(II)-catalyzed asymmetric hydrogenation of ~ketoesters gave up to 96% ee involving a practical and reproducible procedure using the defined and readily prepared [2.2]PHANEPHOS-Ru(lI)bis(trifluoroacetate) salt in the presence of a halide source.

📜 SIMILAR VOLUMES

ChemInform Abstract: [2.2]PHANEPHOS-Ruth
ChemInform Abstract: [2.2]PHANEPHOS-Ruthenium(II) Complexes: Highly Active Asymmetric Catalysts for the Hydrogenation of β-Ketoesters.
✍ P. J. PYE; K. ROSSEN; R. A. REAMER; R. P. VOLANTE; P. J. REIDER 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

1998 stereochemistry stereochemistry (general, optical resolution) O 0030 37 -036 [2.2]PHANEPHOS-Ruthenium(II) Complexes: Highly Active Asymmetric Catalysts for the Hydrogenation of β-Ketoesters. -Ru(II)-complexes of planar chiral [2.2]PHANEPHOS are found to be highly efficient catalysts for the as