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Abnormal N-Heterocyclic Carbene-Phosphine Ruthenium(II) Complexes as Active Catalysts for Transfer Hydrogenation

✍ Scribed by Witt, Julia; Pöthig, Alexander; Kühn, Fritz E.; Baratta, Walter

Book ID
120557494
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
532 KB
Volume
32
Category
Article
ISSN
0276-7333

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Active ruthenium-(N-heterocyclic carbene
Active ruthenium-(N-heterocyclic carbene) complexes for hydrogenation of ketones
✍ Murat Yiǧit; Beyhan Yiǧit; İsmail Özdemir; Engin Çetinkaya; Bekir Çetinkaya 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 126 KB 👁 2 views

Four ruthenium-N-heterocyclic carbene complexes (3-6) have been prepared and the new compounds characterized by C, H, N analyses, 1 H-NMR and 13 C-NMR. The reduction of ketones to alcohols via transfer hydrogenation was achieved with catalytic amounts of complexes 3-6 in the presence of t-BuOK.