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Active ruthenium-(N-heterocyclic carbene) complexes for hydrogenation of ketones

✍ Scribed by Murat Yiǧit; Beyhan Yiǧit; İsmail Özdemir; Engin Çetinkaya; Bekir Çetinkaya

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
126 KB
Volume
20
Category
Article
ISSN
0268-2605

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✦ Synopsis

Four ruthenium-N-heterocyclic carbene complexes (3-6) have been prepared and the new compounds characterized by C, H, N analyses, 1 H-NMR and 13 C-NMR. The reduction of ketones to alcohols via transfer hydrogenation was achieved with catalytic amounts of complexes 3-6 in the presence of t-BuOK.

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