The molecule of the title compound, a Schiff base, C 9 H 7 ClN 2 S 2 , is roughly planar, with the two rings twisted by only 8.8 . Molecules are interconnected by weak C-HÁ Á ÁS interactions leading to the formation of chains parallel to the c axis. Weak slippedstacking between the thiophene rings m
2-[(5-Methylthiazol-2-ylimino)methyl]phenol
✍ Scribed by Zhang, Chun-Niu ;Yang, Ming-Hua ;Zheng, Yun-Fa
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 104 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title molecule, C 11 H 10 N 2 OS, the benzene ring makes a dihedral angle of 6.4 (2) with the thiazole ring. The expected electron delocalization is observed in the -C-N CH-imino system.
📜 SIMILAR VOLUMES
The title compound, C 13 H 18 N 2 O 2 , exists in the enol-imine tautomeric form with a strong intramolecular O-HÁ Á ÁN hydrogen bond [OÁ Á ÁN = 2.5795 (18) A ˚], and the morpholine ring adopts an almost perfect chair conformation.
The crystal structure of the title compound, C 22 H 20 N 2 O 2 , is stabilized by C-HÁ Á ÁO, C-HÁ Á Á andinteractions. The central benzene ring forms dihedral angles of 58.55 (6) and 4.02 (6) with the terminal benzene rings.