The title compound, C 14 H 24 N + ÁI À , was formed by a Schiff base condensation of 2,6-diisopropylaniline and acetone, using GaI as a Lewis acid. A strong interaction from the iminium hydrogen NÐH to the iodide counter-ion is observed. The 1 H and 13 C NMR data are also reported.
2-[(2,6-Diisopropylphenyl)iminio]propyl bromide
✍ Scribed by Zhang, Fan ;Lerner, Hans-Wolfram ;Bolte, Michael
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 238 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, C 24 H 28 O 5 , the keto group is planar. Weak CÐHÁ Á ÁO hydrogen bonds play a signi®cant role in the crystal packing.
The ortho-disubstituted aromatic ring in the title compound, C 27 H 32 N 2 , is twisted by 76.1 (1) with respect to the isopropylsubstituted ring and by 89.3 (1) with respect to the methylsubstituted ring. The amino N atom is linked intramolecularly to the imino N by a hydrogen bond [NÁ Á ÁN = 2.686
In the molecule of the title Schiff base, C 19 H 22 FN, the fluorinebearing aromatic ring makes an angle of 68.0 (1) with the other sterically crowded aromatic ring.