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2-[(2,6-Diiso­propyl­phenyl)­iminio]­propyl bromide

✍ Scribed by Zhang, Fan ;Lerner, Hans-Wolfram ;Bolte, Michael


Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
238 KB
Volume
59
Category
Article
ISSN
1600-5368

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📜 SIMILAR VOLUMES


(2,6-Diiso­propyl­phenyl)­iso­propyl­ide
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The title compound, C 14 H 24 N + ÁI À , was formed by a Schiff base condensation of 2,6-diisopropylaniline and acetone, using GaI as a Lewis acid. A strong interaction from the iminium hydrogen NÐH to the iodide counter-ion is observed. The 1 H and 13 C NMR data are also reported.

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In the title compound, C 24 H 28 O 5 , the keto group is planar. Weak CÐHÁ Á ÁO hydrogen bonds play a signi®cant role in the crystal packing.

2-[2-(2,6-Di­methyl­phenyl­amino)­phenyl
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The ortho-disubstituted aromatic ring in the title compound, C 27 H 32 N 2 , is twisted by 76.1 (1) with respect to the isopropylsubstituted ring and by 89.3 (1) with respect to the methylsubstituted ring. The amino N atom is linked intramolecularly to the imino N by a hydrogen bond [NÁ Á ÁN = 2.686

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In the molecule of the title Schiff base, C 19 H 22 FN, the fluorinebearing aromatic ring makes an angle of 68.0 (1) with the other sterically crowded aromatic ring.