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N-(2-Fluoro­benzyl­idene)-2,6-diiso­propyl­aniline

✍ Scribed by Gao, Hai-Yang ;Lü, Xing-Qiang ;Bao, Feng ;Wu, Qing ;Ng, Seik Weng

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
126 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the molecule of the title Schiff base, C 19 H 22 FN, the fluorinebearing aromatic ring makes an angle of 68.0 (1) with the other sterically crowded aromatic ring.

📜 SIMILAR VOLUMES

(2,6-Diiso­propyl­phenyl)­iso­propyl­ide
(2,6-Diiso­propyl­phenyl)­iso­propyl­idene­ammonium iodide
✍ Baker, Robert J. ;Bettentrup, Helga ;Jones, Cameron 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 154 KB

The title compound, C 14 H 24 N + ÁI À , was formed by a Schiff base condensation of 2,6-diisopropylaniline and acetone, using GaI as a Lewis acid. A strong interaction from the iminium hydrogen NÐH to the iodide counter-ion is observed. The 1 H and 13 C NMR data are also reported.

N-(2-Nitro­benzyl­idene)aniline
N-(2-Nitro­benzyl­idene)aniline
✍ Naveen, S. ;Anil Kumar, K. ;Channe Gowda, D. ;Sridhar, M. A. ;Shashidhara Prasad 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 128 KB
N-(4-Bromo­benzyl­idene)-2-hydroxy­anili
N-(4-Bromo­benzyl­idene)-2-hydroxy­aniline
✍ Jiao, Yuan-Hong ;Zhang, Qian ;Ng, Seik Weng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 105 KB

N-(4-Bromobenzylidene)-2-hydroxyaniline, C 13 H 10 BrNO, exists as a planar molecule in which the hydroxy group is intramolecularly hydrogen bonded to the imino N atom.