N-[2-(Benzylsulfanyl)benzylidene]-2-(methylsulfanyl)aniline
✍ Scribed by Hamaker, Christopher G. ;Maryashina, Oksana ;Halbach, Dominic P.
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 260 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The title compound, C~25~H~24~N~2~O~3~S~3~, was crystallized from a methanol–acetone mixture. The monoclinic structure features one molecule in the asymmetric unit. The crystal packing is stabilized by π stacking.
The title molecule, C 20 H 20 N 2 O 2 S, exits in the Z form and the five-membered imidazole ring and the benzene ring of the 4methoxybenzylidene moiety are almost coplanar. Short intramolecular contacts [CÁ Á ÁS = 3.138 (4) A ˚and CÁ Á ÁN = 3.060 (4) A ˚] indicate the presence of weak C-HÁ Á ÁS and
In the crystal structure of the title compound, C 21 H 21 PS 3 , two crystallographically independent molecules are found. One of these molecules is located in a general position, whereas the P atom of the second molecule is located on a threefold rotation axis.