The geometrical parameters for the title compound, C 16 H 13 NO 2 S, are normal. The non-centrosymmetric crystal packing, which is consistent with the non-zero second harmonic generation response, may be influenced by a weak intermolecular C-HÁ Á ÁO interaction.
Tris[2-(methylsulfanyl)phenyl]phosphine
✍ Scribed by Uttecht, Jan-Georg ;Tuczek, Felix ;Näther, Christian
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 166 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
In the crystal structure of the title compound, C 21 H 21 PS 3 , two crystallographically independent molecules are found. One of these molecules is located in a general position, whereas the P atom of the second molecule is located on a threefold rotation axis.
📜 SIMILAR VOLUMES
The geometrical parameters for the title compound, C 16 H 13 ClOS, are normal. The dihedral angle between the two benzene rings is 48.16 (5) . The non-centrosymmetric crystal packing is consistent with the substantial non-zero second harmonic generation response.
The molecule of the title compound, C 22 H 29 NOS, is nonplanar, with a dihedral angle of 32.06 (9) between the two aromatic rings.