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N-(4-Bromo­benzyl­idene)-2-hydroxy­aniline

✍ Scribed by Jiao, Yuan-Hong ;Zhang, Qian ;Ng, Seik Weng

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
105 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

N-(4-Bromobenzylidene)-2-hydroxyaniline, C 13 H 10 BrNO, exists as a planar molecule in which the hydroxy group is intramolecularly hydrogen bonded to the imino N atom.

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The title compound, C 13 H 11 N 3 O 2 , was prepared by the reaction of pyridine-4-carboxylic acid hydrazide and phydroxybenzaldehyde in ethanol. In the crystal structure, all non-H atoms are coplanar, with an r.m.s. deviation of 0.096 A ˚. N-HÁ Á ÁN, O-HÁ Á ÁN and O-HÁ Á ÁO intermolecular hydrogen