By meam of 5OOMHz 'H two-dimensional correlated NMR spectroscopy and the 62.89--C two-dimemional hadequate technique, all proton and carbon cbemid shifts of 1-methoxy-endetetracy-cl0[6.3.0.@''.@~]undec-9-ene can be assigned m an unambiguous way.
1H and 13C NMR studies on 1-methoxy-endo-tetracyclo[6.3.0.02,11.03,7]undec-9-ene
✍ Scribed by A. W. H. Jans; J. Lugtenburg; J. Cornelisse; C. Kruk
- Publisher
- John Wiley and Sons
- Year
- 1982
- Tongue
- English
- Weight
- 270 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
High field NMR spectroscopy, including nuclear Overhauser effect experiments and homonuclear decoupling techniques, provide conclusive evidence for the structure of 1‐methoxy‐endo‐tetracyclo[6.3.0.0^2,11^.0^3,7^]undec‐9‐enundec‐9‐ene. The ^13^C NMR spectrum has been recorded and the carbon shifts have been assigned by using SFORD spectra and selective decoupling experiments.
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