✦ LIBER ✦
Nucleophilic Addition to C,C-Double Bonds. Part VIII. The standard enthalpies of formation of anti9,10-10endo-hydroxytricyclo [4.2.1.12,5]deca-3,7-dien-9-one and 9-Oxatetracyclo [5.4.0.03,10.04,8]undec-5-en-2-one and kinetic data for the cyclization of the olefinic alcohol to the ether
✍ Scribed by Alan A. Smeaton; William V. Steele; Gerardo M. Ramos Tombo; Camille Ganter
- Publisher
- John Wiley and Sons
- Year
- 1983
- Tongue
- German
- Weight
- 258 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Abstract
In view of the significance of steric compression in the base‐catalyzed intramolecular cyclization of polycyclic olefinic alcohols, the standard enthalpies of formation of anti^9,10^‐10 endo‐hydroxytricyclo [4.2.1.1^2,5^]deca‐3,7‐dien‐9‐one (1) and 9‐oxatetracyclo [5.4.0.0^3,10^.0^4,8^]undec‐5‐en‐2‐one (2) as well as the kinetics of the ether formation 1 → 2 were determined.