𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A 1H and 13C NMR study of 4,8,9,10-tetraaryl-1,3-diazatricyclo[3.3.1.13,7]decan-6-ones

✍ Scribed by V. Vijayakumar; M. Sundaravadivelu; S. Perumal; A. Lycka

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
85 KB
Volume
39
Category
Article
ISSN
0749-1581

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The ^1^H and ^13^C NMR spectra of 4,8,9,10‐tetraaryl‐1,3‐diazatricyclo[3.3.1.13, 7]decan‐6‐ones were measured at 400 and 500 and at 100 and 125 MHz, respectively. The chemical shifts were assigned unambiguously using one‐ and two‐dimensional (H,H‐COSY, C,H‐COSY, NOESY, ROESY and HMBC) NMR spectroscopic data. 1D‐INADEQUATE data also provide an independent assignment of the signals of the carbons of the heterocyclic rings. These results clearly indicate the axial orientation of two aryl groups in one piperidone ring and the equatorial orientation, of the other two aryl groups in another ring. Copyright © 2001 John Wiley & Sons, Ltd.

📜 SIMILAR VOLUMES

1H and 13C NMR spectral assignments of s
1H and 13C NMR spectral assignments of some novel 2,4,6,8-tetraaryl-3,7-diazabicyclo[3.3.1]nonan-9-one derivatives
✍ Paramasivam Parthiban; Rajamanickam Ramachandran; Gopalakrishnan Aridoss; Sentha 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 136 KB

## Abstract The ^1^H and ^13^C NMR spectra of 2,4,6,8‐tetraaryl‐3,7‐diazabicyclo[3.3.1]nonan‐9‐ones (1–2), oximes (3–8) and __O__‐benzyl oximes (9–12) were recorded. The chemical shifts were unambiguously assigned using 1D and 2D NMR spectral data. The results clearly indicate that the compounds ex

1H and 13C NMR study of stereoisomers of
1H and 13C NMR study of stereoisomers of 3-(arylpropenylidene)isobenzofuran-1(3H)-ones
✍ Nikolay N. Sveshnikov; Victor I. Nikulin 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 269 KB

## Abstract A study of the ^1^H and ^13^C NMR spectra of a series of __E,E__‐ and __Z,E__‐isomers of 3‐(arylpropenylidene)isobenzofuran‐1 (3__H__)‐ones [1a–d and 2a–d, respectively] was carried out. The __E,E__‐ and __Z,E__‐isomers 1a–d and 2a–d were recognized by the local anisotropy effect of the

1H and 13C NMR spectra of C-6 and C-9 su
1H and 13C NMR spectra of C-6 and C-9 substituted 3-azabicyclco[3.3.1]nonanes
✍ Kirsten Goodall; Margaret Brimble; David Barker 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 168 KB

## Abstract The ^1^H and ^13^C NMR data for 3‐azabicyclo[3.3.1]nonanes with OH and OMe substituents at C‐6 and C‐9 were measured using 1D (DEPT) and 2D (COSY, HSQC, HMBC, NOESY) experiments. Comparison of this NMR data illustrates the effects of stereochemistry and substitution at these positions.

1H and 13C NMR study of 6-aryl-3-cinchop
1H and 13C NMR study of 6-aryl-3-cinchopheny-1,2,4-triazolo[3,4-b]-1,3,4-thiadiazoles
✍ Xue-hui Liu; Hao Xu; Yi-ou Fang; Yu-xin Cui; Peng-fei Xu 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 81 KB

## Abstract Ten new 1,2,4‐triazolo[3,4‐__b__]‐1,3,4‐thiadiazole derivatives were synthesized and their NMR spectra were analyzed by 1D and 2D NMR techniques (gCOSY, gHMBC, gHMQC). Copyright © 2001 John Wiley & Sons, Ltd.

13C NMR study of tetrahydrothiazolo-[3,2
13C NMR study of tetrahydrothiazolo-[3,2-d][1,4]benzodiazepin-3[2H]-ones
✍ M. Zappalá; G. Romeo; S. Grasso; A. Chimirri; A. M. Mon-Forte 📂 Article 📅 1989 🏛 John Wiley and Sons 🌐 English ⚖ 262 KB

The complete assignments of the 13C NMR resonances for eight tetrahydrothiazolo [3,2-d] [1,4] benzodiazepin-3(2H)-ones are reported. The data obtained account for a conformational rigidity of the heptatomic ring as a consequence of the annelation of the thiazolidinone nucleus. KEY WORDS '3C NMR Tetr