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1H, 13C and 77Se NMR spectra of substituted selenoanisoles

✍ Scribed by G. A. Kalabin; D. F. Kushnarev; V. M. Bzesovsky; G. A. Tschmutova

Publisher: John Wiley and Sons
Year: 1979
Tongue: English
Weight: 788 KB
Volume: 12
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1270121011

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The ^1^H, ^13^C and ^77^Se chemical shifts and the ^1^J[C(Me)H(Me)], ^1.2^J(SeC) and ^2^J(SeH) coupling constants in 14 para‐ or meta‐substituted selenoanisoles, RC~6~H~4~SeCH~3~, have been measured and the dependence of these parameters on the electronic effects of the substituent R is discussed. A significant (up to 6 ppm) deviation from additivity of the substituent influence on the shielding of the ^13^C ring carbons has been found.

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