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77Se, 13C and 1H NMR spectra of acyclic phenylselenenylalkanes and -alkenes and some of their selenoxides

✍ Scribed by Helmut Duddeck; Petra Wagner; Barbara Rys

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
602 KB
Volume
31
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The ^77^Se, ^13^C and ^1^H NMR spectra of 57 mostly new compounds with phenylselenenyl groups attached to acyclic alkanes, alkenes and phenylalkanes and of 10 corresponding selenoxides are reported. Substituent effects on the chemical shifts of these nuclei were determined and are discussed in terms of the conformation and configuration. The results suggest that, in contrast to PhSeCCSePh fragments, CCCSe chains prefer a gauche conformation.

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