13C and 77Se NMR spectra of thienoisoselenazoles, selenoloisothiazoles, selenoloisoselenazoles and thienoisothiazoles
โ Scribed by N. V. Onyamboko; M. Renson; S. Chapelle; P. Granger
- Publisher
- John Wiley and Sons
- Year
- 1982
- Tongue
- English
- Weight
- 362 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0749-1581
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โฆ Synopsis
Abstract
The ^13^C and ^77^Se NMR spectra of eight new unsubstituted biheterocycles containing a thiophene or selenophene ring condensed with an isothiazole or isoselenazole ring were recorded. The assignments of the ^13^C signals were made by the examination of chemical shifts, ^1^J(CH) coupling constants and, for the quaternary carbons, on the basis of ^1^J(C, ^77^Se) coupling constants. The results are compared and discussed.
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## Abstract The ^77^Se, ^13^C and ^1^H NMR spectra of the products of phenylselenenyl azide and chloride addition to methylenecyclohexane and cyclohexene are presented. Scalar couplings between ^77^Se and ^1^H/^13^C allowed the absolute assignment of the regioisomers in the ^1^H and ^13^C spectra.
## Abstract ^77^Se and ^13^C chemical shift of 19 1,2,3โselenadiazoles are discussed in terms of substituent effects and conformaโtional behaviour of the molecules. It is shown that the ^77^Se chemical shifts of such compounds are suitable tools for chiral discrimination in diastereomeric compounds
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